The Giallorosse won 3-1 at Petershill Park, whereas the French side saw off Servette with a 3-0 triumph earlier the same day.
The two sides will now face off at the same venue at 19:00 CEST (18:00 local time) on Sunday.
Here's what you need to know about the contest...
Roma have now won 11 of their last 12 away trips in all competitions, drawing the other. It is as many as they won in the 24 away games prior to that (five draws, eight defeats).
Alessandro Spugna's side have scored 49 goals in all competitions since the start of the calendar year; only Juventus (53) have done better among Italian sides.
Paris FC finished third in Ligue 1 last season, picking up 50 points in total (16 wins, two draws, four defeats).
They scored 49 goals in the league last term, a tally beaten by only Paris Saint-Germain and Olympique Lyonnais.
The game against Glasgow saw Valentina Giacinti, Moeka Minami and Norma Cinotti all make their Roma debuts.
For Lucia Di Guglielmo, Giada Greggi, Moeka Minami and Norma Cinotti it was also their debut in the Women's Champions League.
Paloma Lazaro has scored more goals than any other Roma player since the start of 2022, with nine in all competitions. Benedetta Glionna sits joint second with five (alongside Emilie Haavi).
The French side have only three overseas players in their ranks: Chiamaka Nnadozie (Nigerian), Coumba Sow and Eseosa Aigbogun (both Swiss).
Clara Mateo, who scored a brace against Servette in the last round, was her side's top goalscorer in Ligue 1 last season with 11 goals.
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